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Germanium monosulfide : ウィキペディア英語版
Germanium monosulfide

Germanium monosulfide or Germanium(II) sulfide is the chemical compound with the formula GeS. It is a chalcogenide glass and a semiconductor. Germanium sulfide is described as a red-brown powder or black crystals. Germanium(II) sulfide when dry is stable in air, hydrolyzes slowly in moist air but rapidly reacts in water forming Ge(OH)2 and then GeO.〔E. G. Rochow, E. W. Abel ,1973, The Chemistry of Germanium Tin and Lead, Pergamon Press, ISBN 0-08-018854-0〕 It is one of a few sulfides that can be sublimed under vacuum without decomposition.〔Michael Binnewies, Robert Glaum, Marcus Schmidt, Peer Schmidt, 2012, Chemical Vapor Transport Reactions, De Gruyter, ISBN 978-3-11-025464-8〕
==Preparation==
First made by Winkler by reducing GeS2 with Ge.〔 Other methods include reduction in a stream of H2 gas,〔 or with an excess of H3PO2 followed by vacuum sublimation.〔

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